Synthesis And Raman Spectroscopic Studies of NaZr2(PO4)3

被引：1
|
作者：
Kamali, K. [1 ]
Ravindran, T. R. [1 ]
Sridharan, V. [1 ]
Nithya, R. [1 ]
机构：
[1] Indira Gandhi Ctr Atom Res, Mat Sci Grp, Kalpakkam 603102, Tamil Nadu, India
来源：
SOLID STATE PHYSICS, PTS 1 AND 2 | 2012年 / 1447卷
关键词：
NZP; sol gel method; NTE; Raman spectroscopy; EXPANSION; CERAMICS; FAMILY; RANGE;
D O I：
10.1063/1.4710256
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Sodium Zirconium Phosphate (NaZr2(PO4)(3)), a low thermal expansion material is synthesized by aqueous sol gel method. Raman spectroscopic studies are carried out as a function of temperature from 80 K to 860 K. The modes at 72 and 423 cm(-1) exhibit a positive temperature coefficient which points to their negative role in thermal expansion. These modes are due to the translational motion of Na atoms and rotational motion of PO4 ions respectively, and it is conceivable that they contribute to negative thermal expansion in this material.
引用
收藏
页码：823 / 824
页数：2
相关论文
共 50 条
  • [41] Synthesis, luminescence, and biocompatibility of calcium- and lanthanide-containing NaZr2(PO4)3-type compounds
    A. I. Orlova
    A. E. Kanunov
    E. N. Gorshkova
    A. N. Shushunov
    S. N. Pleskova
    E. R. Mikheeva
    D. O. Savinykh
    E. S. Leonov
    Inorganic Materials, 2013, 49 : 89 - 94
  • [42] Preparation and Thermal Expansion of Calcium Iron Zirconium Phosphates with the NaZr2(PO4)3 Structure
    D. O. Savinykh
    S. A. Khainakov
    A. I. Orlova
    S. Garcia-Granda
    Inorganic Materials, 2018, 54 : 591 - 595
  • [43] Fabrication of NaZr2(PO4)3-type ceramic materials by spark plasma sintering
    Orlova, A. I.
    Koryttseva, A. K.
    Kanunov, A. E.
    Chuvil'deev, V. N.
    Moskvicheva, A. V.
    Sakharov, N. V.
    Boldin, M. S.
    Nokhrin, A. V.
    INORGANIC MATERIALS, 2012, 48 (03) : 313 - 317
  • [44] Preparation and Thermal Expansion of Calcium Iron Zirconium Phosphates with the NaZr2(PO4)3 Structure
    Savinykh, D. O.
    Khainakov, S. A.
    Orlova, A. I.
    Garcia-Granda, S.
    INORGANIC MATERIALS, 2018, 54 (06) : 591 - 595
  • [45] Erbium zirconium phosphate Er0.33Zr2(PO4)3 of the NaZr2(PO4)3 family. Structure contraction on heating
    A. I. Orlova
    S. G. Samoilov
    G. N. Kazantsev
    V. Yu. Volgutov
    A. Yu. Kazakova
    Radiochemistry, 2010, 52 (6) : 666 - 669
  • [46] Fabrication of NaZr2(PO4)3-type ceramic materials by spark plasma sintering
    A. I. Orlova
    A. K. Koryttseva
    A. E. Kanunov
    V. N. Chuvil’deev
    A. V. Moskvicheva
    N. V. Sakharov
    M. S. Boldin
    A. V. Nokhrin
    Inorganic Materials, 2012, 48 : 313 - 317
  • [47] Synthesis, luminescence, and biocompatibility of calcium- and lanthanide-containing NaZr2(PO4)3-type compounds
    Orlova, A. I.
    Kanunov, A. E.
    Gorshkova, E. N.
    Shushunov, A. N.
    Pleskova, S. N.
    Mikheeva, E. R.
    Savinykh, D. O.
    Leonov, E. S.
    INORGANIC MATERIALS, 2013, 49 (01) : 89 - 94
  • [48] Erbium Zirconium Phosphate Er0.33Zr2(PO4)(3) of the NaZr2(PO4)(3) Family. Structure Contraction on Heating
    Orlova, A. I.
    Samoilov, S. G.
    Kazantsev, G. N.
    Volgutov, V. Yu.
    Kazakova, A. Yu.
    RADIOCHEMISTRY, 2010, 52 (06) : 666 - 669
  • [49] 载银NaZr2（PO4）3粉体的制备及其抗菌性
    卢凯雯
    童莉媛
    江栩婷
    钟玉璇
    吴德武
    龙岩学院学报, 2025, 43 (02) : 59 - 64
  • [50] Anharmonic phonons of NaZr2( PO4)3 studied by Raman spectroscopy, first-principles calculations, and x-ray diffraction
    Kamali, K.
    Ravindran, T. R.
    Ravi, C.
    Sorb, Y.
    Subramanian, N.
    Arora, A. K.
    PHYSICAL REVIEW B, 2012, 86 (14)
12345