Synthesis and Molecular Structure of 2-(4-Chlorophenyl)-3-(phenyl-amino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4H-imidazol-4-one

被引：0

作者：

Sharma, Devinder K. ^{[1
]}

Subbulakshmi, K. N. ^{[2
]}

Narayana, B. ^{[2
]}

Sarojini, B. K. ^{[3
]}

Anthal, Sumati ^{[1
]}

Kant, R. ^{[1
]}

机构：

[1] Univ Jammu, Dept Phys, Xray Crystallog Lab, Jammu, India

[2] Mangalore Univ, Dept Chem, Mangalagangothri, DK, India

[3] Mangalore Univ, Dept Ind Chem, Mangalagangothri, DK, India

来源：

CRYSTALLOGRAPHY REPORTS | 2017年 / 62卷 / 07期

关键词：

IMIDAZOLE; INHIBITION; RESINS;

D O I：

10.1134/S1063774517070082

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

2-(4-Chlorophenyl)-3-(phenylamino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4H-imidazol-4-one, C20H14N3OSCl was synthesized and its crystal structure was determined by single crystal X-ray diffraction. The crystals are triclinic, sp. gr. P1, Z = 2. All three rings are planar, and imidazole ring is almost perpendicular to the phenyl ring with the dihedral angle of 88.65(2)degrees. In the crystal, pairs of O-H center dot center dot center dot O hydrogen bonds link molecules into inversion dimers, featuring R-22(10) graph set motif. Crystal structure is further stabilized by pi center dot center dot center dot pi interactions.

引用

页码：1148 / 1151

页数：4

共 50 条

[1] Synthesis and Molecular Structure of 2-(4-Chlorophenyl)-3-(phenyl-amino)-5-(thiophen-2-ylmethylidene)-3,5-dihydro-4H-imidazol-4-one
Devinder K. Sharma
K. N. Subbulakshmi
B. Narayana
B. K. Sarojini
Sumati Anthal
R. Kant
Crystallography Reports, 2017, 62 : 1148 - 1151
[2] 3-(4-Chlorophenyl)-5-(thiophen-2-yl)-4,5-dihydro-1H-pyrazole-1-carbothioamide
Fun, Hoong-Kun
Suwunwong, Thitipone
Chantrapromma, Suchada
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O259 - U1464
[3] Synthesis, structure and electrochemistry of CoIILCl2•0.5MeCN{L = [2-(methylthio)-3-phenyl-5-(pyridin-2-ylmethylene)-3,5-dihydro-4H-imidazol-4-one]}
Majouga, AG
Beloglazkina, EK
Vatsadze, SZ
Moiseeva, AA
Butin, KP
Zyk, NV
MENDELEEV COMMUNICATIONS, 2004, 14 (03) : 115 - 117
[4] Synthesis 5-(pyrazolin-3-ylmethylidene)-2-thiohydantoins and 2-alkylsulfanyl-5-(pyrazolin-3-ylmethylidene)-3,5-dihydro-4H-imidazol-4-ones
Vorozhtsov, N. I.
Sviridova, L. A.
Grigorkevich, O. S.
Korablina, D. D.
Beloglazkina, E. K.
Majouga, A. G.
Zyk, N. V.
RUSSIAN CHEMICAL BULLETIN, 2017, 66 (03) : 506 - 510
[5] Synthesis 5-(pyrazolin-3-ylmethylidene)-2-thiohydantoins and 2-alkylsulfanyl-5-(pyrazolin-3-ylmethylidene)-3,5-dihydro-4H-imidazol-4-ones
N. I. Vorozhtsov
L. A. Sviridova
O. S. Grigorkevich
D. D. Korablina
E. K. Beloglazkina
A. G. Majouga
N. V. Zyk
Russian Chemical Bulletin, 2017, 66 : 506 - 510
[6] 5-(2-chlorophenyl)-3-(4-chlorophenyl)-1-phenyl-2-pyrazoline
Guo, Huan-Mei
Jian, Fang-Fang
Zhao, Pu-Su
Zhang, Yun-Chen
Li, Yu-Feng
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O215 - O216
[7] Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one
Kayalvizhi, M.
Vasuki, G.
Kumar, R. Raj
Rao, V. Rajeswar
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O1268 - +
[8] 5-(4-chlorophenyl)-3-(4-nitrophenyl)-1-phenyl-2-pyrazoline
Guo, Huan-Mei
Jian, Fang-Fang
Li, Yu-Feng
Lin, Cui-Hua
Wu, Qian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O1814 - O1815
[9] Molecular structure and vibrational spectra of 2-[5-(4-chlorophenyl)-4,5-dihydro-1H-pyrazol-3-yl]phenol
Sawant, A. B.
Gill, C. H.
Nirwan, R. S.
INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2012, 50 (01) : 38 - 44
[10] 3-(4-bromophenyl)-5-(4-chlorophenyl)-1-phenyl-2-pyrazoline
Guo, Huan-Mei
Jian, Fang-Fang
Xiao, Hai-Lian
Sun, Xiao-Zheng
Li, Yu-Feng
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : o1435 - o1436

← 1 2 3 4 5 →