Tetrabutylammonium iodide catalyzed allylic sulfonylation of Baylis-Hillman acetates with sulfonylhydrazides in water

被引：105
|
作者：
Li, Xiaoqing [1 ]
Xu, Xiangsheng [1 ]
Tang, Yucai [1 ]
机构：
[1] Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2013年 / 11卷 / 10期
基金：
中国国家自然科学基金;
关键词：
METAL-FREE; OXIDATIVE AMINATION; RADICALS; SULFONES; DERIVATIVES; BONDS; TBHP;
D O I：
10.1039/c3ob27329f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A tetrabutylammonium iodide catalyzed method for the synthesis of allyl aryl sulfone derivatives with Baylis-Hillman acetates and sulfonylhydrazides using tert-butyl hydroperoxide as an oxidation agent in water has been developed. In this process, the group eliminated from the sulfonyl precursor is molecular nitrogen.
引用
收藏
页码：1739 / 1742
页数：4
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