Influence of the ionic liquid on the rate and the mechanism of reaction of p-nitrophenyl acetate with secondary alicyclic amines

被引：17

作者：

Millan, Daniela ^{[1
]}

Rojas, Mabel ^{[1
]}

Pavez, Paulina ^{[1
]}

Isaacs, Mauricio ^{[2
]}

Diaz, Carlos ^{[2
]}

Santos, Jose G. ^{[1
]}

机构：

[1] Pontificia Univ Catolica Chile, Fac Quim, Dept Fisicoquim, Santiago, Chile

[2] Pontificia Univ Catolica Chile, Dept Quim Inorgan, Santiago, Chile

来源：

NEW JOURNAL OF CHEMISTRY | 2013年 / 37卷 / 10期

关键词：

SOLVATOCHROMIC COMPARISON METHOD; SUBSTITUTED PYRIDINES; NONLEAVING GROUP; PAIR FORMATION; TEMPERATURE; PYRIDINOLYSIS; AMINOLYSIS; SOLVENTS; KINETICS; NUCLEOFUGALITY;

D O I：

10.1039/c3nj00781b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of p-nitrophenyl acetate (1) with piperidine was studied in nine organic solvents and in nine ionic liquids. The aminolysis of 1 by four different secondary amines was also studied in [Bmim]BF4 and their basicities were determined in this solvent using two different methods. Medium effects were analysed and interpreted by comparing the rate constants of aminolysis for the two sets of solvents.

引用

页码：3281 / 3288

页数：8

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