Thin-Film Cu-Pt(111) Near-Surface Alloys: Active Electrocatalysts for the Oxygen Reduction Reaction

被引：45

作者：

Henry, John B. ^{[1
]}

Maljusch, Artjom

Huang, Minghua ^{[1
]}

Schuhmann, Wolfgang ^{[1
]}

Bondarenko, Alexander S. ^{[1
]}

机构：

[1] Ruhr Univ Bochum, CES, D-44780 Bochum, Germany

来源：

ACS CATALYSIS | 2012年 / 2卷 / 07期

关键词：

near-surface alloys; ORR; electrocatalysis; Pt(111)-like thin films; CATALYSTS; PLATINUM;

D O I：

10.1021/cs300165t

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple method is presented for the formation of thin films of Cu-Pt(111) near-surface alloys (NSA). In these thin films, the solute metal (Cu) is preferentially located in the second platinum layer and protected by a Pt surface layer. The NSA films act as active and fairly stable electrocatalysts for the reduction of oxygen with the activity and stability which approach those for bulk single crystalline Pt alloy surfaces, and similar to 5 times more active than state-of-the-art Pt thin films.

引用

页码：1457 / 1460

页数：4

共 50 条

[21] Dealloyed PdCu3 thin film electrocatalysts for oxygen reduction reaction
Yang, Ruizhi
Bian, Weiyong
Strasser, Peter
Toney, Michael F.
JOURNAL OF POWER SOURCES, 2013, 222 : 169 - 176
[22] Beneficial compressive strain for oxygen reduction reaction on Pt (111) surface
Kattel, Shyam
Wang, Guofeng
JOURNAL OF CHEMICAL PHYSICS, 2014, 141 (12):
[23] Mechanically activated Pt-Ni and Pt-Co alloys as electrocatalysts in the oxygen reduction reaction
Cortes-Escobedo, Claudia A.
Gonzalez-Huerta, Rosa de G.
Bolarin-Miro, Ana M.
Sanchez de Jesus, Felix
Zhu, Q.
Canton, S. E.
Suarez-Alcantara, Karina
Tufino-Velazquez, M.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (29) : 16722 - 16730
[24] LIGHT-SATURATION IN THE REACTION OF OXYGEN REDUCTION ON THE SURFACE OF PHOTOCATHODE WITH THIN-FILM OF ZINC PHTHALOCYANIN
ILATOVSKII, VA
KOMISSAROV, GG
ZHURNAL FIZICHESKOI KHIMII, 1991, 65 (04): : 1075 - 1077
[25] First principles investigation of the activity of thin film Pt, Pd and Au surface alloys for oxygen reduction
Tripkovic, Vladimir
Hansen, Heine Anton
Rossmeisl, Jan
Vegge, Tejs
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (17) : 11647 - 11657
[26] The oxygen reduction reaction on thin palladium films supported on a Pt(111) electrode
Arenz, M
Schmidt, TJ
Wandelt, K
Ross, PN
Markovic, NM
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (36): : 9813 - 9819
[27] An accurate evaluation for the activity of nano-sized electrocatalysts by a thin-film rotating disk electrode: Oxygen reduction on Pt/C
Ke, Ke
Hiroshima, Kazutaka
Kamitaka, Yuji
Hatanaka, Tatsuya
Morimoto, Yu
ELECTROCHIMICA ACTA, 2012, 72 : 120 - 128
[28] Oxygen reduction reaction on thin-film Ag electrodes in alkaline solution
Linge, Jonas Mart
Erikson, Heiki
Kasikov, Aarne
Rahn, Mihkel
Sammelselg, Vaino
Tammeveski, Kaido
ELECTROCHIMICA ACTA, 2019, 325
[29] Electrochemical reduction of oxygen on thin-film Pt electrodes in 0.1 M KOH
Tammeveski, K
Tenno, T
Claret, J
Ferrater, C
ELECTROCHIMICA ACTA, 1997, 42 (05) : 893 - 897
[30] Hollow PtCu octahedral nanoalloys: Efficient bifunctional electrocatalysts towards oxygen reduction reaction and methanol oxidation reaction by regulating near-surface composition
Chen, Guorong
Yang, Xiaotong
Xie, Zixuan
Zhao, Fengling
Zhou, Zhiyou
Yuan, Qiang
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2020, 562 (562) : 244 - 251

← 1 2 3 4 5 →