Investigation of room temperature hydrogen storage in biomass derived activated carbon

被引:49
|
作者
Samantaray, Sai Smruti [1 ]
Mangisetti, Sandhya Rani [1 ]
Ramaprabhu, S. [1 ]
机构
[1] Indian Inst Technol Madras, Dept Phys, Alternat Energy & Nanotechnol Lab, Chennai 600036, Tamil Nadu, India
关键词
Activated carbon; Hydrogen storage; KOH activation; Biomass precursor; POROUS CARBONS; CAPACITY; MECHANISM;
D O I
10.1016/j.jallcom.2019.03.110
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Overcoming the barrier of hydrogen storage is a promising avenue to a zero emission fuel economy. In the present study, we demonstrate that a balance between pore size, pore volume and large surface area of activated Carbon material helps in achieving increased hydrogen uptake at room temperature and moderate pressures. The activated carbon material, synthesized using a biomass precursor and the KOH activation process, furnishes a high surface area of similar to 2090 m(2)/g and a pore volume of 1.44 cm(3) /g.The hydrogen adsorption studies exhibits a good hydrogen uptake capacity of similar to 1.06 wt% at 15 bar equilibrium hydrogen pressure and 25 degrees C signifying that this activated carbon prepared using biomass Palimera sprout can be used for catalyst support material for enhancing the hydrogen uptake capacity by spill over mechanism. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:800 / 804
页数:5
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