New hydrogen bonding motifs of phosphine oxides with a silanediol, a phenol, and chloroform

被引：12

作者：

Kharel, Sugam ^{[1
]}

Bhuvanesh, Nattamai ^{[1
]}

Gladysz, John A. ^{[1
]}

Blumel, Janet ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, POB 30012, College Stn, TX 77842 USA

来源：

INORGANICA CHIMICA ACTA | 2019年 / 490卷

基金：

美国国家科学基金会;

关键词：

Hydrogen bonding; Phosphine oxides; Silanols; Phenols; Chloroform; SOLID-STATE; ANGLE DISTRIBUTION; CRYSTAL-STRUCTURE; CATALYSTS; NMR; SILICA; INSIGHTS; LINKERS; ADDUCTS; REDUCTION;

D O I：

10.1016/j.ica.2019.03.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new hydrogen bonding motifs of phosphine oxides involving a silanol, a phenol, and chloroform are described. The single crystal X-ray structures, in combination with the NMR and IR data of the new adducts Ph3PO center dot HOSiPh2OSiPh2OH center dot OPPh3, which features a linear Si-O-Si linkage, Cy3PO center dot HO(2,6-Bu-t(2)-4-Me(C6H2), and Cy3PO center dot HCCl3, are reported and discussed.

引用

页码：215 / 219

页数：5

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