New hydrogen bonding motifs of phosphine oxides with a silanediol, a phenol, and chloroform

被引：12
|
作者：
Kharel, Sugam [1 ]
Bhuvanesh, Nattamai [1 ]
Gladysz, John A. [1 ]
Blumel, Janet [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, POB 30012, College Stn, TX 77842 USA
来源：
INORGANICA CHIMICA ACTA | 2019年 / 490卷
基金：
美国国家科学基金会;
关键词：
Hydrogen bonding; Phosphine oxides; Silanols; Phenols; Chloroform; SOLID-STATE; ANGLE DISTRIBUTION; CRYSTAL-STRUCTURE; CATALYSTS; NMR; SILICA; INSIGHTS; LINKERS; ADDUCTS; REDUCTION;
D O I：
10.1016/j.ica.2019.03.019
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new hydrogen bonding motifs of phosphine oxides involving a silanol, a phenol, and chloroform are described. The single crystal X-ray structures, in combination with the NMR and IR data of the new adducts Ph3PO center dot HOSiPh2OSiPh2OH center dot OPPh3, which features a linear Si-O-Si linkage, Cy3PO center dot HO(2,6-Bu-t(2)-4-Me(C6H2), and Cy3PO center dot HCCl3, are reported and discussed.
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页码：215 / 219
页数：5
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