Amberlyst-15 as a new and reusable catalyst for regioselective ring-opening reactions of epoxides to β-alkoxy alcohols

被引：90
|
作者：
Liu, Yu-Heng [1 ]
Liu, Qiu-Shuang [1 ]
Zhang, Zhan-Hui [1 ]
机构：
[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 296卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
Amberlyst-15; Heterogeneous catalyst; Ring opening; Epoxide; beta-Alkoxy alcohol; Ultrasound;
D O I：
10.1016/j.molcata.2008.09.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Amberlyst-15 serves as an inexpensive, effective, and environmental friendly heterogeneous catalyst for the regioselective ring-opening of epoxides by primary, secondary and tertiary alcohols, resulted in the formation of beta-alkoxy alcohols in 40-95% yields under ultrasound irradiation. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：42 / 46
页数：5
相关论文
共 50 条
  • [21] Graphite oxide: a simple and efficient solid acid catalyst for the ring-opening of epoxides by alcohols
    Mirza-Aghayan, Maryam
    Alizadeh, Mahdi
    Tavana, Mahdieh Molaee
    Boukherroub, Rabah
    [J]. TETRAHEDRON LETTERS, 2014, 55 (49) : 6694 - 6697
  • [22] Stereoselective Ring-Opening Reactions of Epoxides in Water
    Bonollo, S.
    Lanari, D.
    Marrocchi, A.
    Vaccaro, L.
    [J]. CURRENT ORGANIC SYNTHESIS, 2011, 8 (03) : 319 - 329
  • [23] Aza-Michael reactions with vinyl sulfones and Amberlyst-15 as catalyst
    Esteves, Ana P.
    Silva, Marilia E.
    Rodrigues, Ligia M.
    Oliveira-Campos, Ana M. F.
    Hrdina, Radim
    [J]. TETRAHEDRON LETTERS, 2007, 48 (51) : 9040 - 9043
  • [24] Hβ zeolite: An Efficient and Reusable Catalyst for Ring-Opening of Epoxides with Amines Under Microwave Irradiation
    Rukhsana I. Kureshy
    Santosh Agrawal
    Manish Kumar
    Noor-ul H. Khan
    Sayed H. R. Abdi
    Hari C. Bajaj
    [J]. Catalysis Letters, 2010, 134 : 318 - 323
  • [25] Ytterbium trifluoromethanesulfonate Yb(OTf) (3):: An efficient, reusable catalyst for highly selective formation of β-alkoxy alcohols via ring-opening of 1,2-epoxides with alcohols (June, pg 836, 2001)
    Likhar, PR
    Kumar, MP
    Bandyopadhyay, AK
    [J]. SYNLETT, 2001, (07) : 1196 - 1196
  • [26] Hβ zeolite: An Efficient and Reusable Catalyst for Ring-Opening of Epoxides with Amines Under Microwave Irradiation
    Kureshy, Rukhsana I.
    Agrawal, Santosh
    Kumar, Manish
    Khan, Noor-ul H.
    Abdi, Sayed H. R.
    Bajaj, Hari C.
    [J]. CATALYSIS LETTERS, 2010, 134 (3-4) : 318 - 323
  • [27] REGIOSELECTIVE AND CHEMOSELECTIVE RING-OPENING OF EPOXIDES TO BROMOHYDRINS WITH DILITHIUM TETRABROMOCUPRATE
    CIACCIO, JA
    HELLER, E
    TALBOT, A
    [J]. SYNLETT, 1991, (04) : 248 - 250
  • [28] REGIOSELECTIVE AND STEREOSELECTIVE RING-OPENING OF EPOXIDES WITH AMIDE CUPRATE REAGENTS
    YAMAMOTO, Y
    ASAO, N
    MEGURO, M
    TSUKADA, N
    NEMOTO, H
    SADAYORI, N
    WILSON, JG
    NAKAMURA, H
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (15) : 1201 - 1203
  • [29] Highly regioselective ring-opening of epoxides with thiophenols in ionic liquids without the use of any catalyst
    Chen, JX
    Wu, HY
    Jin, C
    Zhang, XX
    Xie, YY
    Su, WK
    [J]. GREEN CHEMISTRY, 2006, 8 (04) : 330 - 332
  • [30] BF3/HY as a microporous solid acid catalyst for regioselective ring-opening of epoxides
    Yao, Yi-Xuan
    Zhang, Hong-Wei
    Lu, Chang-Bo
    Wang, Xue
    Zhao, Shi-Dong
    Shang, Hong-Yan
    Tian, Yuan-Yu
    [J]. REACTION CHEMISTRY & ENGINEERING, 2023, 8 (12) : 3096 - 3103
12345