The interaction of N,N′-bis(2,6-dimethylphenyl)imidazol-2-ylidene with o-benzosemiquinonato zinc(II) and indium(III) complexes

被引：19

作者：

Ilyakina, Ekaterina V. ^{[1
]}

Poddel'sky, Andrey I. ^{[1
]}

Piskunov, Alexandr V. ^{[1
]}

Fukin, Georgii K. ^{[1
]}

Bogomyakov, Artem S. ^{[2
]}

Cherkasov, Vladimir K. ^{[1
]}

Abakumov, Gleb A. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia

[2] Russian Acad Sci, Int Tomog Ctr, Siberian Branch, Novosibirsk 630090, Russia

来源：

NEW JOURNAL OF CHEMISTRY | 2012年 / 36卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

N-HETEROCYCLIC CARBENE; TRANSITION-METAL-COMPLEXES; MOLECULAR-STRUCTURE; LIGANDS; ALUMINUM; ADDUCTS; GALLIUM;

D O I：

10.1039/c2nj40490g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The N-heterocyclic carbene N,N'-bis(2,6-dimethylphenyl)imidazol-2-ylidene (NHC) interacts with non-transition metal complexes bearing redox-active o-benzosemiquinonato ligands in two ways: as a neutral donor or as a reducer. The reaction of NHC with (3,6-SQ)(2)Zn.Et2O gives the carbene adduct (3,6-SQ)(2)Zn.{CN(Me2Ph)(CH)(2)N(Me2Ph)} (1) while reaction with (3,6-SQ)(3)In forms the ionic complex [(3,6-SQ)(2)(3,6-Cat)In](-) {HCN(Me2Ph)(CH)(2)N(Me2Ph)}(+) (2) as the main product.

引用

页码：1944 / 1948

页数：5

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