Comprehensive approach to the validation of the standard method for total reflection X-ray fluorescence analysis of water

被引：31

作者：

Borgese, Laura ^{[1
,2
]}

Dalipi, Rogerta ^{[1
,2
,3
]}

Riboldi, Alessandro ^{[1
,2
]}

Bilo, Fabjola ^{[1
,2
]}

Zacco, Annalisa ^{[1
,2
]}

Federici, Stefania ^{[1
,2
]}

Bettinelli, Maurizio ^{[4
]}

Bontempi, Elza ^{[1
,2
]}

Depero, Laura Eleonora ^{[1
,2
]}

机构：

[1] Univ Brescia, INSTM, Via Branze 38, I-25123 Brescia, Italy

[2] Univ Brescia, Chem Technol Lab, Dept Mech & Ind Engn, Via Branze 38, I-25123 Brescia, Italy

[3] Ist Zooprofilattico Sperimentale Lombardia & Emil, Via Antonio Bianchi 7-9, I-25124 Brescia, Italy

[4] UNICHIM Assoc Unificaz Settore Ind Chimica, Milan, Italy

来源：

TALANTA | 2018年 / 181卷

关键词：

Water; TXRF; Validation; Calibration; Elements; MULTIELEMENT ANALYSIS; SAMPLES; SPECTROMETRY; UNCERTAINTY; STRATEGIES;

D O I：

10.1016/j.talanta.2017.12.087

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this work, we present the validation of the chemical method for total reflection X-ray fluorescence (TXRF) analysis of water, proposed as a standard to the International Standard Organization. The complete experimental procedure to define the linear calibration range, elements sensitivities, limits of detection and quantification, precision and accuracy is presented for a commercial TXRF spectrometer equipped with Mo X-ray tube. Least squares linear regression, including all statistical tests is performed separately for each element of interest to extract sensitivities. Relative sensitivities with respect to Ga, as internal standard, are calculated. Accuracy and precision of the quantification procedure using Ga as internal standard is evaluated with reference water samples. A detailed discussion on the calibration procedure and the limitation of the use of this method for quantitative analysis of water is presented.

引用

页码：165 / 171

页数：7

共 50 条

[1] Summary of ISO standard 20289: Total reflection X-ray fluorescence analysis of water
Borgese, Laura
Bilo, Fabjola
Federici, Stefania
Margui, Eva
Hase, Thomas
Huang, Yuying
Beckhoff, Burkhard
Depero, Laura E.
SURFACE AND INTERFACE ANALYSIS, 2020, 52 (03) : 119 - 123
[2] Rapid Water Quality Analysis by Total Reflection X-ray Fluorescence Analysis
Miyazaki, Rihoko
Kunimura, Shinsuke
BUNSEKI KAGAKU, 2023, 72 (1-2) : 51 - 55
[3] Development and validation of a method for multielement analysis of apatite by total-reflection X-ray fluorescence spectrometry
Maltsev, Artem S.
Ivanov, Alexei, V
Chubarov, Victor M.
Pashkova, Galina, V
Panteeva, Svetlana, V
Reznitskii, Leonid Z.
TALANTA, 2020, 214
[4] Total reflection x-ray fluorescence analysis - a review
Wobrauschek, P.
X-RAY SPECTROMETRY, 2007, 36 (05) : 289 - 300
[5] Analysis of Beverages by Total Reflection X-ray Fluorescence
Schmeling, Martina
SPECTROSCOPY, 2017, 32 (07) : 28 - 29
[6] A Review of Application of Total Reflection X-ray Fluorescence Spectrometry to Water Analysis
Pashkova, G. V.
Revenko, A. G.
APPLIED SPECTROSCOPY REVIEWS, 2015, 50 (06) : 443 - 472
[7] Total reflection X-ray fluorescence
Schmeling, Martina
PHYSICAL SCIENCES REVIEWS, 2019, 4 (07)
[8] Sources of error in total reflection X-ray fluorescence analysis and error correction using the internal standard method
Pavlinskii, GV
Smagunova, AN
Karpukova, OM
Bolormaa, O
Dorzh, D
JOURNAL OF ANALYTICAL CHEMISTRY, 2002, 57 (03) : 185 - 193
[9] Sources of Error in Total Reflection X-Ray Fluorescence Analysis and Error Correction Using the Internal Standard Method
G. V. Pavlinskii
A. N. Smagunova
O. M. Karpukova
O. Bolormaa
D. Dorzh
Journal of Analytical Chemistry, 2002, 57 : 185 - 193
[10] Sources of error in total-reflection X-ray fluorescence analysis and error correction with the internal standard method
Pavlinskij, G.V.
Smagunova, A.N.
Marpukova, O.M.
Bolormaa, O.
Dorzh, D.
Zhurnal Analiticheskoj Khimii, 2002, 57 (03): : 231 - 240

← 1 2 3 4 5 →