Synthetic Applications of Polystyrene-Supported 1,1,3,3-Tetramethylguanidine

被引:5
|
作者
Coelho, Alberto [1 ]
Crespo, Abel [1 ]
Fernandez, Franco [2 ]
Biagini, PierFrancesco [1 ]
Stefanachi, Angela [1 ]
Sotelo, Eddy [1 ,2 ]
机构
[1] Univ Santiago de Compostela, IFI, Unidad Quim Combinatoria, Santiago De Compostela 15782, Spain
[2] Univ Santiago de Compostela, Fac Farm, Dept Quim Organ, Santiago De Compostela 15782, Spain
关键词
Supported reagents; TMG; base;
D O I
10.2174/138620708786734253
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Several applications of polystyrene-supported 1,1,3,3-tetramethylguanidine (PS-TMG) in synthetic organic chemistry have been explored. This study evidenced the effectiveness and versatility of this new member of the supported guanidine superbases as an attractive candidate to replace the bases usually employed in organic synthesis during the implementation of environmentally friendly preparative processes. [GRAPHICS]
引用
收藏
页码:843 / 847
页数:5
相关论文
共 50 条
  • [21] CONDUCTOMETRIC TITRATIONS IN 1,1,3,3-TETRAMETHYLGUANIDINE - STUDY OF WEAK ACIDS INDICATORS AND NITROAROMATIC COMPOUNDS
    ANDERSON, ML
    HAMMER, RN
    ANALYTICAL CHEMISTRY, 1968, 40 (06) : 940 - &
  • [23] 1,1,3,3-Tetramethylguanidine solvated lanthanide aryloxides: pre-catalysts for intramolecular hydroalkoxylation
    Janini, Thomas E.
    Rakosi, Robert, III
    Durr, Christopher B.
    Bertke, Jeffrey A.
    Bunge, Scott D.
    DALTON TRANSACTIONS, 2009, (47) : 10601 - 10608
  • [24] Physicochemical properties of binary mixtures of 1,1,3,3-tetramethylguanidine imidazolide ionic liquid with water and alcohols
    Ye, Fangfang
    Zhu, Jiahong
    Yu, Keke
    Zhu, Ruyu
    Xu, Yingjie
    Chen, Jiayi
    Chen, Lingxiao
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2016, 97 : 39 - 47
  • [25] Copper-Catalyzed N-Arylation of 1,1,3,3-Tetramethylguanidine Phenyl Isocyanate Adduct
    Yavari, Issa
    Nematpour, Manijeh
    HELVETICA CHIMICA ACTA, 2014, 97 (08) : 1132 - 1135
  • [26] SYNTHESIS AND PROPERTIES OF PHENYL SUBSTITUTED DERIVATIVES OF 2-PHENYL-1,1,3,3-TETRAMETHYLGUANIDINE
    PRUSZYNSKI, P
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (03): : 626 - 629
  • [27] CONDUCTANCES AND DISSOCIATION OF SOME 5-SUBSTITUTED TETRAZOLES IN 1,1,3,3-TETRAMETHYLGUANIDINE AT 25 DEGREES
    CARUSO, JA
    SEARS, PG
    POPOV, AI
    JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (06): : 1756 - &
  • [28] Crosslinking of waterborne polyurethane using dibromide as a crosslinker and 1,1,3,3-tetramethylguanidine (TMG) as an esterification promotor
    Kai, Zheng
    Shan, Pengfei
    Wei, Hongjin
    Qi, Yuxi
    Wen, Xuehao
    Xin, Ge
    Jiang, Jiabin
    Zhang, Ming
    Li, Zhihui
    Li, Zhongyu
    PROGRESS IN ORGANIC COATINGS, 2023, 181
  • [29] Immobilized 1,1,3,3-Tetramethylguanidine Ionic Liquids as the Catalyst for Synthesizing Propylene Glycol Methyl Ether
    Liang, Shuguang
    Zhou, Yinxi
    Liu, Huizhen
    Jiang, Tao
    Han, Buxing
    CATALYSIS LETTERS, 2010, 140 (1-2) : 49 - 54
  • [30] Immobilized 1,1,3,3-Tetramethylguanidine Ionic Liquids as the Catalyst for Synthesizing Propylene Glycol Methyl Ether
    Shuguang Liang
    Yinxi Zhou
    Huizhen Liu
    Tao Jiang
    Buxing Han
    Catalysis Letters, 2010, 140 : 49 - 54