Unusual reactions of a cationic carbyne complex of manganese with carbonyliron dianions to form a novel dimetal carbene-bridged complex [MnFe{mu-C(COEt)Ph}(eta-C5H5)(CO)(5)]

被引：19

作者：

Yu, Y

Chen, JB

Chen, J

Zheng, PJ

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,ORGANOMET CHEM LAB,SHANGHAI 200032,PEOPLES R CHINA

[2] FUDAN UNIV,RES CTR ANAL & MEASUREMENT,SHANGHAI 200433,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 07期

关键词：

D O I：

10.1039/dt9960001443

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Mn(=CPh)(eta-C5H5)(CO)(2)]BBr4 1 with [NEt(4)](2)[Fe-2(CO)(8)] in tetrahydrofuran at low temperature gave a novel heteronuclear dimetal carbene-bridged complex [MnFe{mu-C(COEt)Ph}(eta-C5H5)(CO)(5)] 3, and a dimetal dicarbene complex [{(OC)(2)(eta-C5H5)Mn(=CPh)}Fe-2(2)(CO)(8)] 4, as well as [Mn(eta-C5H5)-(CO)(3)] 2. The same products, 2 and 3, were obtained from the reaction of 1 with Na-2[Fe(CO)(4)]. The structure of 3 has been established by X-ray crystallography.

引用

页码：1443 / 1447

页数：5

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