Dynamic control of ligand conformation: Asymmetric epoxidation using achiral (salen)manganese(III) complex

被引：0
|
作者：
Miura, K [1 ]
Katsuki, T [1 ]
机构：
[1] Kyushu Univ, Grad Sch Sci, Dept Mol Chem, Higashi Ku, Fukuoka 8128581, Japan
来源：
SYNLETT | 1999年 / 06期
关键词：
asymmetric epoxidation; (salen)manganese(III) complex; dynamic stereocontrol;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
High enantioselectivity and good chemical yields were realized in the epoxidation of 2,2-dimethylchromene derivatives using achiral (salen)manganese(III) complex 5 as a catalyst in the presence of axially chiral bipyridine N,N'-dioxide 4.
引用
收藏
页码：783 / 785
页数：3
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