Dynamic control of ligand conformation: Asymmetric epoxidation using achiral (salen)manganese(III) complex

被引：0
|
作者：
Miura, K [1 ]
Katsuki, T [1 ]
机构：
[1] Kyushu Univ, Grad Sch Sci, Dept Mol Chem, Higashi Ku, Fukuoka 8128581, Japan
来源：
SYNLETT | 1999年 / 06期
关键词：
asymmetric epoxidation; (salen)manganese(III) complex; dynamic stereocontrol;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
High enantioselectivity and good chemical yields were realized in the epoxidation of 2,2-dimethylchromene derivatives using achiral (salen)manganese(III) complex 5 as a catalyst in the presence of axially chiral bipyridine N,N'-dioxide 4.
引用
收藏
页码：783 / 785
页数：3
相关论文
共 50 条
  • [1] The first asymmetric epoxidation using a combination of achiral (salen)manganese(III) complex and chiral amine
    Hashihayata, T.
    Ito, Y.
    Katsuki, T.
    Tetrahedron, 53 (28):
  • [2] The first asymmetric epoxidation using a combination of achiral (salen)manganese(III) complex and chiral amine
    Hashihayata, T
    Ito, Y
    Katsuki, T
    TETRAHEDRON, 1997, 53 (28) : 9541 - 9552
  • [3] Asymmetric Epoxidation of Olefins with Homogeneous Chiral (Salen) Manganese (III) Complex
    Shi, Qian-Ping
    Shi, Zhi-Hao
    Li, Nian-Guang
    Tang, Yu-Ping
    Li, Wei
    Tang, Hao
    Wei-Zhang
    Shen, Min-Zhe
    Duan, Jin-Ao
    CURRENT ORGANIC CHEMISTRY, 2013, 17 (23) : 2936 - 2970
  • [4] CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS USING CHIRAL (SALEN)MANGANESE(III) COMPLEXES
    IRIE, R
    NODA, K
    ITO, Y
    MATSUMOTO, N
    KATSUKI, T
    TETRAHEDRON-ASYMMETRY, 1991, 2 (07) : 481 - 494
  • [5] CATALYTIC ASYMMETRIC EPOXIDATION WITH (SALEN)MANGANESE(III) COMPLEX BEARING BINAPHTHYL GROUPS OF AXIAL CHIRALITY
    SASAKI, H
    IRIE, R
    KATSUKI, T
    SYNLETT, 1993, (04) : 300 - 302
  • [6] Advances in the asymmetric epoxidation of double bond using salen manganese(III) complexes as catalysts
    Wang, XY
    Shi, HC
    Xu, SY
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2001, 21 (12) : 1102 - 1111
  • [7] New chiral (salen)manganese(III) systems for asymmetric epoxidation of styrene
    Wei, Saili
    Tang, Yuhai
    Xu, Guojin
    Tang, Xiaoshuang
    Ling, Yongjin
    Li, Rui
    Sun, Yang
    REACTION KINETICS AND CATALYSIS LETTERS, 2009, 97 (02): : 329 - 333
  • [8] New chiral (salen)manganese(III) systems for asymmetric epoxidation of styrene
    Saili Wei
    Yuhai Tang
    Guojin Xu
    Xiaoshuang Tang
    Yongjin Ling
    Rui Li
    Yang Sun
    Reaction Kinetics and Catalysis Letters, 2009, 97 : 329 - 333
  • [9] ASYMMETRIC OXIDATION OF SULFIDES USING (SALEN)MANGANESE(III) COMPLEX AS A CATALYST
    NODA, K
    HOSOYA, N
    YANAI, K
    IRIE, R
    KATSUKI, T
    TETRAHEDRON LETTERS, 1994, 35 (12) : 1887 - 1890
  • [10] New capacity of (salen)manganese complexes:: Asymmetric oxidation of C-H σ-bond and dynamic control of ligand conformation
    Katsuki, T
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1999, 57 (10) : 824 - 834
12345