Polymeric monovalent and divalent copper sulfates with 4.4′-bipyridine:: [CU2(SO4)(4,4′-bipy)2 • 6H2O]n and [CU(SO4)(4,4′-bipy)(H2O) • 0.5H2O]n

被引：18
|
作者：
Lah, N [1 ]
Leban, I [1 ]
机构：
[1] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 01期
关键词：
copper complex; coordination polymer; sulfate coordination; bipyridine; solvothermal synthesis;
D O I：
10.1016/j.inoche.2005.07.026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new composite inorganic-organic materials from the copper/sulfate/4,4'-bipyridine family have been isolated and structurally characterized. The structure of the monovalent compound exhibits double chains in which the two parallel -Cu-bipy- chains are interconnected through sulfate bridges. The divalent polymer consists of two-dimensional interwoven networks that are stacked together by hydrogen bonding between the layers. (c) 2005 Elsevier B.V. All rights reserved.
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收藏
页码：42 / 45
页数：4
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