Formation of linear polymers with pendant vinyl groups via inclusion complex mediated polymerization of divinyl monomers

被引：19

作者：

Satav, Sunita S.

Karmalkar, Rohini N.

Kulkarni, Mohan G. ^{[1
]}

Mulpuri, Nagaraju

Sastry, G. Narahari

机构：

[1] Natl Chem Lab, Polymer Sci & Engn Div, Pune 411008, Maharashtra, India

[2] Indian Inst Chem Technol, Mol Modeling Grp, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 24期

关键词：

D O I：

10.1021/ja062568z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ethylene glycol dimethacrylate (EGDMA) and ethylene glycol methacrylate 4-vinyl benzoate (EGMAVB) were shown to form 1:1 inclusion complexes with cyclodextrin and were characterized by instrumental techniques. Computational analysis showed that the bent conformation of the included divinyl monomer was more stable than its linear conformation. Complexation of the divinyl monomer with the first CD molecule offered substantial stabilization than with the second CD molecule. The vinyl group included in the CD cavity did not participate in polymerization. As a result, solvent soluble, linear polymers with pendant vinyl unsaturation per repeat unit were obtained. This was unequivocally established by the polymerization of a complex comprising CD and EGMAVB. The unreacted vinyl group can be polymerized in the subsequent step to yield cross-linked products. Copyright © 2006 American Chemical Society.

引用

页码：7752 / 7753

页数：2

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