Deposition of LDH on plasma treated polylactic acid to reduce water permeability

被引:21
|
作者
Bugatti, Valeria [1 ,2 ]
Livi, Sebastien [2 ,3 ,4 ,5 ]
Hayrapetyan, Suren [2 ]
Wang, Yue [2 ]
Estevez, Luis [2 ]
Vittoria, Vittoria [1 ]
Giannelis, Emmanuel P. [2 ,6 ]
机构
[1] Univ Salerno, Dept Ind Engn, I-84084 Fisciano, SA, Italy
[2] Cornell Univ, Dept Mat Sci & Engn MSE, Ithaca, NY 14853 USA
[3] Univ Lyon, F-69003 Lyon, France
[4] INSA Lyon, F-69621 Villeurbanne, France
[5] CNRS, UMR 5223, F-69621 Villeurbanne, France
[6] King Fahd Univ Petr & Minerals, Ctr Refining & Petrochem, Dhahran 31261, Saudi Arabia
关键词
Ionic liquids; Oxygen plasma; PLA coatings; Layered double hydroxide; LAYERED DOUBLE HYDROXIDES; IONIC LIQUIDS; BARRIER PROPERTY; FREE-VOLUME; FILMS; COATINGS; NANOCOMPOSITES; SORPTION; OXYGEN; VAPOR;
D O I
10.1016/j.jcis.2013.01.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple and scalable deposition process was developed to prepare polylactic acid (PLA) coatings with enhanced water barrier properties for food packaging applications. This method based on electrostatic interactions between the positively charged layers of layered double hydroxides (LDHs) modified with ionic liquids (ILs) and the negatively charged plasma treated polylactic acid leads to homogeneous, stable, and highly durable coatings. Deposition of the LDH coatings increases the surface hydrophobicity of the neat PLA, which results to a decrease in water permeability by about 35%. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码:47 / 52
页数:6
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