Copper-catalyzed three-component phosphorylation-peroxidation of alkenes

被引：33
|
作者：
Chen, Yan [1 ]
Chen, Yuanjin [1 ]
Lu, Shenglin [1 ]
Li, Zhiping [1 ]
机构：
[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 06期
基金：
美国国家科学基金会;
关键词：
P-H COMPOUNDS; CARBONYLATION-PEROXIDATION; UNACTIVATED ALKENES; ALPHA; BETA-UNSATURATED ESTERS; RADICAL-ADDITION; NATURAL-PRODUCTS; P(O)-H COMPOUNDS; SINGLET OXYGEN; BOND FORMATION; T-HYDRO;
D O I：
10.1039/c7qo01045a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A copper-catalyzed phosphorylation-peroxidation of alkenes has been developed. The three-component protocol provides practical access to multisubstituted -phosphoryl peroxides by the reactions of P(O)-H compounds, alkenes and tert-butyl hydroperoxide (TBHP). The obtained -phosphoryl peroxides can be applied to the synthesis of -phosphoryl epoxides by using lithium bis(trimethylsilyl)amide (LHMDS) as a base.
引用
收藏
页码：972 / 976
页数：5
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