Sulfur rich microporous polymer enables rapid and efficient removal of mercury(II) from water

被引:61
|
作者
Xu, Dan [1 ,2 ]
Wu, Winston Duo [3 ]
Qi, Hao-Jun [1 ]
Yang, Rui-Xia [2 ]
Deng, Wei-Qiao [2 ]
机构
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Dept Polymer Sci & Engn, Jiangsu Key Lab Adv Funct Polymer Design & Applic, Suzhou 215123, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
[3] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Sch Chem & Environm Engn, Suzhou Key Lab Green Chem Engn, Suzhou 215123, Peoples R China
关键词
Microporous polymer; Sulfur rich; Mercury(II) removal; Water treatment; Adsorption; COVALENT ORGANIC FRAMEWORKS; AQUEOUS-SOLUTION; CARBON NANOTUBES; IONS; ADSORPTION; HG2+; HG(II); NANOCOMPOSITES; SORPTION; EXCHANGE;
D O I
10.1016/j.chemosphere.2017.12.186
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Design and synthesis of adsorbents for efficient decontamination of hazardous contaminants Hg2+ from wastewater, based on a facile and economical strategy, is an attractive target. Here, a novel sulfur rich microporous polymer (sulfur content of 31.4 wt %) with high surface area as well as densely populated sulfur atom with fast accessibility was reported to remove mercury (II) from water. The as prepared polymer (SMP) exhibited high binding affinity, high adsorption capacities, rapid adsorption kinetics, and good recyclability for Hg2+. The adsorption capacity of SMP was 595.2 mg Furthermore, SMP could reduce trace concentrations of Hg2+ from 200 p. p. b. to a level below drinking water standards (2 p. p. b.) within 3 min. This work allows large-scale production of sulfur rich porous materials for the practical application in water treatment. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:174 / 181
页数:8
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