A Thermoanalytical Study of Mixtures of Polyvinyl Alcohol with Succinic Acid after Plastic Deformation under High Pressure

被引：1

作者：

Zhorin, V. A. ^{[1
]}

Kiselev, M. R. ^{[2
]}

Kotenev, V. A. ^{[2
]}

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia

[2] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 117915, Russia

来源：

PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES | 2017年 / 53卷 / 06期

关键词：

FLOW; POLYMERS;

D O I：

10.1134/S2070205117060247

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

Mixtures of polyvinyl alcohol and amber acid of different composition were subjected to plastic deformation under the pressure of 1.5 GPa at the equipment of the Bridgman-anvil type and the DSC method was used to study heat processes in nondeformed and deformed samples. It is shown that two processes occur simultaneously in PVA under heating: the endothermal process of decomposition of intermolecular bonds and mass decrease related to loss of adsorbed water. After plastic deformation, a decrease in the enthalpy of melting occurred in both components of the PVC-amber-acid mixtures. A low-temperature phase with T (melt) 30-40A degrees C lower than in the initial polymer was formed in the acid and a decrease in the relaxation process enthalpy was observed in the polymer.

引用

页码：1075 / 1081

页数：7

共 50 条

[21] Melting of high- and low-density polyethylene in mixtures with aluminum after plastic deformation under high pressure
V. A. Zhorin
M. R. Kiselev
V. A. Kotenev
Protection of Metals and Physical Chemistry of Surfaces, 2017, 53 : 703 - 710
[22] Heat effects in high-density polyethylene after plastic deformation in mixtures with metal oxides under high pressure
Zhorin, VA
Kiselev, MR
Roldugin, VI
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2002, 76 (02): : 194 - 199
[23] Melting of High-and Low-Density Polyethylene in Mixtures with Aluminum after Plastic Deformation under High Pressure
Zhorin, V. A.
Kiselev, M. R.
Kotenev, V. A.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2017, 53 (04) : 703 - 710
[24] Thermomechanical, Differential Scanning Calorimetry, and Electron Microscopic Study of Al-Cu Mixtures after Plastic Deformation under High Pressure
Zhorin, V. A.
Kiselev, M. R.
Gulin, A. A.
Kotenev, V. A.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2023, 59 (03) : 389 - 395
[25] Thermal processes in succinic acid-aluminum blends subjected to high-pressure plastic deformation
Zhorin, V. A.
Kiselev, M. R.
Roldughin, V. I.
COLLOID JOURNAL, 2017, 79 (05) : 630 - 636
[26] A calorimetric study of the process of formation of a supramolecular high-density polyethylene structure in mixtures with different oxides after plastic deformation under high pressure
V. A. Zhorin
M. R. Kiselev
V. A. Kotenev
Protection of Metals and Physical Chemistry of Surfaces, 2017, 53 : 819 - 825
[27] A calorimetric study of the process of formation of a supramolecular high-density polyethylene structure in mixtures with different oxides after plastic deformation under high pressure
Zhorin, V. A.
Kiselev, M. R.
Kotenev, V. A.
PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2017, 53 (05) : 819 - 825
[28] Calorimetric study of mixtures of various polymers with KMnO4 under high-pressure plastic deformation
Zhorin V.A.
Kiselev M.R.
Roldugin V.I.
Tikhonov A.P.
Doklady Physical Chemistry, 2002, 383 (1-3) : 71 - 74
[29] Thermal Effects in Mixtures of Boric Acid with Some Polymers and Low-Molecular-Weight Inorganic Substances after Plastic Deformation under High Pressure
V. A. Zhorin
M. R. Kiselev
A. V. Grachev
V. Yu. Bychkov
N. V. Avramenko
A. M. Parfenova
V. A. Kotenev
Protection of Metals and Physical Chemistry of Surfaces, 2022, 58 : 1125 - 1134
[30] Some Properties of Aluminum–Copper Mixtures after Plastic Deformation under High Pressures
V. A. Zhorin
M. R. Kiselev
I. I. Bardyshev
V. V. Vysotskii
S. E. Smirnov
V. A. Kotenev
Protection of Metals and Physical Chemistry of Surfaces, 2022, 58 : 501 - 509

← 1 2 3 4 5 →