Open-cage fullerenes as tailor-made container for a single water molecule

被引：63
|
作者：
Shi, Lijun [1 ]
Gan, Liangbing [1 ,2 ]
机构：
[1] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
[2] Acad Sinica, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2013年 / 26卷 / 10期
关键词：
molecular container; water chemistry; fullerene; CARBON NANOTUBES; APPLE PEELS; ENCAPSULATION; C-60; PEROXIDES; CLEAVAGE; C-70; DERIVATIVES; COMPLEXES; ORIFICES;
D O I：
10.1002/poc.3169
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Water is the most important liquid on earth. Clusters of water have been investigated extensively in an effort to understand the bulk property of water. But the behavior of single water molecule without H-bond has been rarely studied. Open-cage [60]fullerenes have been shown to trap a single water molecule selectively over molecules with comparable size and act as the smallest water bottle. Copyright (c) 2013 John Wiley & Sons, Ltd.
引用
收藏
页码：766 / 772
页数：7
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