A method for isotope exchange kinetics in mineral-water system-an in-situ study on oxygen isotope exchange in Na2CO3-H2O system

被引：0
|
作者：
Wang, Shixia [1 ]
Lu, Kaijie [1 ]
Wang, Teng [1 ]
Wu, Jia [2 ]
Zheng, Haifei [3 ]
Huang, Yiguo [1 ]
机构：
[1] Univ Shanghai Sci & Technol, Coll Sci, Shanghai 200093, Peoples R China
[2] China Univ Petr, State Key Lab Petr Resources & Prospecting, Beijing 102249, Peoples R China
[3] Peking Univ, Dept Geol, Key Lab Orogen Belts & Crustal Evolut, Beijing 100871, Peoples R China
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2020年 / 241卷
基金：
中国国家自然科学基金;
关键词：
Oxygen isotope exchange; In-situ Raman spectroscopy; Na2CO3-H2O system; Kinetic study; Hydrothermal diamond anvil cell (HDAC); DIAMOND-ANVIL CELL; HIGH-TEMPERATURE; CARBONIC-ACID; HIGH-PRESSURE; BICARBONATE; CALCITE;
D O I：
10.1016/j.saa.2020.118648
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The experiments on the exchange reaction rate of the oxygen isotopes in the mineral-water system with initial conditions of 100 degrees C and 240 MPa, 100 degrees C and 924 MPa, 118 degrees C and 170 MPa are taken. The oxygen isotope O-18 exchange reactions between aqueous C16O32- and (H2O)-O-18 are mainly traced by measuring the Raman peak intensity of oxygen-containing elements (CO32-) in sodium carbonate solution. The inconsistent trends between the molar fraction and the concentration of (CO2O2-)-O-18-O-16 indicate oxygen isotope exchange between sodium carbonate and heavy water accompanied by dissolution and recrystallization between supersaturated sodium carbonate solution and solid sodium carbonate. In the heterogeneous experimental systems the order of oxygen isotope exchange reactions are more than 1 and the dynamics of oxygen isotope exchange conform to JMAK kinetics model with the nucleation and growth processes of sodium carbonate crystal. (c) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页数：7
相关论文
共 50 条
  • [31] Oxygen-Isotope Exchange between CO2 and Solid Ti18O2
    Civis, Svatopluk
    Ferus, Martin
    Kubat, Pavel
    Zukalova, Marketa
    Kavan, Ladislav
    JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (22): : 11156 - 11162
  • [32] STUDY OF KINETICS, EQUILIBRIUM AND ISOTOPE EXCHANGE IN ION-EXCHANGE SYSTEMS .4. GEL KINETICS OF ION-EXCHANGE IN NA+ - MG2+ - STRONGLY ACIDIC CATION EXCHANGER SYSTEM
    STAMBERG, K
    PLICKA, J
    CABICAR, J
    GOSMAN, A
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1985, 90 (02) : 289 - 302
  • [33] The influence of water-rock reactions and O isotope exchange with CO2 on water stable isotope composition of CO2 springs in SE Australia
    Karolyte, Ruta
    Johnson, Gareth
    Serno, Sascha
    Gilfillan, Stuart M. V.
    13TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, GHGT-13, 2017, 114 : 3832 - 3839
  • [34] Experimental Study of Hydrogen Isotope Kinetic Fractionation Between Ilvaite and Water——The Kinetics of D-H Exchange in Ilvaite-H2O
    钱雅倩
    郭吉保
    Science in China,SerB, 1993, Ser.B1993 (01) : 110 - 120
  • [35] STUDY OF KINETICS OF ION-EXCHANGE IN THE TERNARY-SYSTEM NA+-CO2+-NI2+
    PLICKA, J
    STAMBERG, K
    CABICAR, J
    SPEVACKOVA, V
    REACTIVE POLYMERS, 1988, 7 (2-3): : 141 - 150
  • [36] Oxygen isotope exchange kinetics between H2O and H4SiO4 from ab initio calculations
    Felipe, MA
    Kubicki, JD
    Rye, DM
    GEOCHIMICA ET COSMOCHIMICA ACTA, 2004, 68 (05) : 949 - 958
  • [37] INFLUENCE OF SOLUTION COMPOSITION AND PRESSURE ON THE RATES OF OXYGEN ISOTOPE EXCHANGE IN THE SYSTEM - CALCITE-H2O-NACL AT ELEVATED-TEMPERATURES
    COLE, DR
    CHEMICAL GEOLOGY, 1992, 102 (1-4) : 199 - 216
  • [38] ISOTOPE EXCHANGE IN IRON(2)-IRON(3)-CHLORIDE ION SYSTEM IN DIMETHYL SULFOXIDE
    WADA, G
    REYNOLDS, W
    INORGANIC CHEMISTRY, 1966, 5 (08) : 1354 - &
  • [39] Dynamics of isotope exchange between hyperthermal O(3P) and CO2
    Yeung, Laurence Y.
    Okumura, Mitchio
    Zhang, Jianming
    Minton, Timothy K.
    Paci, Jeffrey T.
    Camden, Jon P.
    Schatz, George C.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [40] Kinetic study on the reaction between CO2-CO and wustite using the isotope exchange method
    Teng Zhang
    Xiao-jun Hu
    Kuo-Chih Chou
    International Journal of Minerals Metallurgy and Materials, 2013, 20 (02) : 125 - 130
12345