Gold-Catalyzed Carbene Transfer Reactions

被引：17
|
作者：
Shin, Seunghoon [1 ,2 ]
机构：
[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea
[2] Hanyang Univ, Ctr New Direct Organ Synth, Seoul 133791, South Korea
来源：
HOMOGENEOUS GOLD CATALYSIS | 2015年 / 357卷
基金：
新加坡国家研究基金会;
关键词：
Carbene transfer; Gold carbene; Gold catalysis; Oxygen atom transfer; ONE-POT SYNTHESIS; INTERMOLECULAR OXIDATION; AZOMETHINE YLIDES; EFFICIENT SYNTHESIS; ALKYNE OXIDATION; TERMINAL ALKYNES; REDOX REACTION; SULFUR YLIDES; N-OXIDES; ACCESS;
D O I：
10.1007/128_2014_589
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In homogeneous gold catalysis, generations and reactions of metal carbenes have been one of the most rapidly developing areas because of their diverse reactivity under mild conditions. This review covers recent advances in the gold-catalyzed oxygen atom transfer and carbene transfer reactions to alkynes. Atom transfer to an alkyne enables alkynes to function as metal carbene synthons. Many such reactions fulfill redox neutrality starting from safe and easily handled precursors.
引用
收藏
页码：25 / 62
页数：38
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