Gold-Catalyzed Carbene Transfer Reactions

被引：17
|
作者：
Shin, Seunghoon [1 ,2 ]
机构：
[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea
[2] Hanyang Univ, Ctr New Direct Organ Synth, Seoul 133791, South Korea
来源：
HOMOGENEOUS GOLD CATALYSIS | 2015年 / 357卷
基金：
新加坡国家研究基金会;
关键词：
Carbene transfer; Gold carbene; Gold catalysis; Oxygen atom transfer; ONE-POT SYNTHESIS; INTERMOLECULAR OXIDATION; AZOMETHINE YLIDES; EFFICIENT SYNTHESIS; ALKYNE OXIDATION; TERMINAL ALKYNES; REDOX REACTION; SULFUR YLIDES; N-OXIDES; ACCESS;
D O I：
10.1007/128_2014_589
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In homogeneous gold catalysis, generations and reactions of metal carbenes have been one of the most rapidly developing areas because of their diverse reactivity under mild conditions. This review covers recent advances in the gold-catalyzed oxygen atom transfer and carbene transfer reactions to alkynes. Atom transfer to an alkyne enables alkynes to function as metal carbene synthons. Many such reactions fulfill redox neutrality starting from safe and easily handled precursors.
引用
收藏
页码：25 / 62
页数：38
相关论文
共 50 条
  • [1] Gold-Catalyzed Sigmatropic Rearrangement Reactions via Carbene Transfer Reactions
    He, Feifei
    Jana, Sripati
    Koenigs, Rene M.
    JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (18): : 11882 - 11891
  • [2] Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates
    Dorel, Ruth
    Echavarren, Antonio M.
    JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (15): : 7321 - 7332
  • [3] Multi C-H Functionalization Reactions of Carbazole Heterocycles via Gold-Catalyzed Carbene Transfer Reactions
    Jana, Sripati
    Empel, Claire
    Nguyen, Thanh Vinh
    Koenigs, Rene M.
    CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (08) : 2628 - 2632
  • [4] Chirality Transfer and Memory of Chirality in Gold-Catalyzed Reactions
    Patil, Nitin T.
    CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (10) : 2186 - 2194
  • [5] C-H Functionalization Reactions of Unprotected N-Heterocycles by Gold-Catalyzed Carbene Transfer
    Jana, Sripati
    Empel, Claire
    Pei, Chao
    Aseeva, Polina
    Nguyen, Thanh, V
    Koenigs, Rene M.
    ACS CATALYSIS, 2020, 10 (17): : 9925 - 9931
  • [6] Gold-Catalyzed Polymerization Based on Carbene Polycyclopropanation
    Nzulu, Frida
    Bontemps, Alexis
    Robert, Julien
    Barbazanges, Marion
    Fensterbank, Louis
    Goddard, Jean-Philippe
    Malacria, Max
    Ollivier, Cyril
    Petit, Marc
    Rieger, Jutta
    Stoffelbach, Francois
    MACROMOLECULES, 2014, 47 (19) : 6652 - 6656
  • [7] Gold-Catalyzed Organic Reactions
    Hashmi, A. Stephen K.
    INVENTING REACTIONS, 2013, 44 : 143 - 164
  • [8] Gold-catalyzed Dearomatization Reactions
    An, Juzeng
    Bandini, Marco
    CHIMIA, 2018, 72 (09) : 610 - 613
  • [9] Gold-catalyzed multicomponent reactions
    Tathe, Akash. G. G.
    Saswade, Sagar. S. S.
    Patil, Nitin. T. T.
    ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (09) : 2359 - 2384
  • [10] Gold-catalyzed organic reactions
    Hashmi, A. Stephen K.
    CHEMICAL REVIEWS, 2007, 107 (07) : 3180 - 3211
12345