A two-dimensional hydrogen bonded organic framework self-assembled from a three-fold symmetric carbamate

被引:23
|
作者
Hou, Xiaodong [1 ]
Wang, Zhihan [1 ]
Overby, Molly [1 ]
Ugrinov, Angel [2 ]
Oian, Casey [1 ]
Singh, Rajiv [1 ]
Chu, Qianli R. [1 ]
机构
[1] Univ N Dakota, Dept Chem, Grand Forks, ND 58202 USA
[2] N Dakota State Univ, Dept Chem & Biochem, Fargo, ND 58102 USA
基金
美国国家科学基金会;
关键词
NETWORKS; DESIGN; INCLUSION; DIVERSITY; CRYSTAL; SOLIDS;
D O I
10.1039/c3cc47159d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A flexible organic sheet spontaneously assembled under mild conditions from a tri-carbamate. By introducing cyclohexyl side chains as 'pillars' between the sheets, a hydrogen bonded organic framework was formed which displayed a capacity for accommodating and releasing guest molecules. The guest size/shape selectivity of the lamellar framework was demonstrated by testing with various guests.
引用
收藏
页码:5209 / 5211
页数:3
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