Synthesis and Spectral Properties of Unsymmetrically Substituted Mn(II) and Mn(III) Octaethylporphyrins

被引：0

作者：

Zvezdina, S. V. ^{[1
]}

Chizhova, N. V. ^{[1
]}

Mamardashvili, N. Zh. ^{[1
]}

机构：

[1] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 56卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

octaethylporphyrin; mono-; trinitrosubstituted octaethylporphyrins and their Cd(II); Mn(II); and Mn(III) complexes; nitration; complexation; metal-exchange reactions; spectral properties; METAL-EXCHANGE-REACTION; MANGANESE PORPHYRIN; OXIDATION; COMPLEXES; KINETICS;

D O I：

10.1134/S1070428020080072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

5-Mononitro-2,3,7,8,12,13,17,18-octaethylporphyrin, 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin, and their Cd(II) complexes were synthesized. The coordination reactions of 2,3,7,8,12,13,17,18-octaethylporphyrin and its mono- and trinitro-substituted derivatives and the metal-exchange reactions of the synthesized Cd(II) octaethylporphyrin complexes with Mn(II) chloride in DMF were investigated by spectrophotometry. The corresponding Mn(II) and Mn(III) porphyrins were obtained and identified. The kinetic parameters of the studied reactions were determined.

引用

页码：1374 / 1382

页数：9

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