A Novel Preparation of Blankophor R Nanoparticles by Reverse Microemulsion Method

被引:1
|
作者
Bani Ali, Elahe [1 ]
Kazemi, Masoud [1 ]
Ali Ghasemzadeh, Mohammad [1 ]
机构
[1] Islamic Azad Univ, Qom Branch, Dept Chem, Post Box 37491-13191, Qom, Iran
关键词
Blankophor R; diameter; fluorescent whitening agent; microemulsion; FLUORESCENT WHITENING AGENTS; SOLID-PHASE EXTRACTION; ORGANIC NANOPARTICLES; MAGNETIC NANOPARTICLES; LAUNDRY DETERGENTS; DYE; BRIGHTENERS; WATER; FWAS;
D O I
10.1080/10406638.2018.1563553
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Blankophor R is an organic compound and a stilbene type of fluorescent whitening agent (FWA). In this research, the preparation of Blankophor R was successfully synthesized using a nucleophilic substitution reaction withphenyl-isocyanate based on 4,4 '-diamino-stilbene-2,2 '-disulfonic acid. The structure of Blankophor R and its intermediates were characterized by spectroscopy techniques. In addition we reported a Blankophor R synthesis of Blankophor R nanoparticles in Reverse microemulsion method. The optimized formulation contains (w/w): water 20%, n-butyl acetate 50%, cetyltrimethylammonium bromide 10%, and isopropanol 20% and Blankophor R in water (%): 0.5. As a result, the microemulsion system was prepared clear, homogeneous and thermodynamically stable. The obtained Blankophor R nanoparticles showed spherical shape with an average diameter 60 nm, based on SEM and TEM images. In this work, the effect of Blankophor R NPs on dye transfer inhibition (DTI) were showed a high stability, leading to excellent DTI effects.
引用
收藏
页码:1595 / 1605
页数:11
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