The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2:: structural comparisons with the analogous silatrane complex Os(Si[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2

被引：42

作者：

Rickard, CEF ^{[1
]}

Roper, WR ^{[1
]}

Woodman, TJ ^{[1
]}

Wright, LJ ^{[1
]}

机构：

[1] Univ Auckland, Dept Chem, Auckland, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 09期

关键词：

D O I：

10.1039/a901408j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first metal substituted stannatrane,Os(Sn-[OCH2CH2](3)N)(eta(2)-S2CNMe2)(CO)(PPh3)(2), has been synthesised by reaction between triethanolamine and the triiodostannyl osmium complex Os(SnI3)(eta(2)-S2CNMe2)-(CO)(PPh3)(2): the transannular Sn-N distance of 2.422(4) Angstrom indicates a bonding interaction which is not seen in the corresponding silatranyl complex Os(Si[OCH2CH2](3)N)(eta(2)-S2CNMe2)(CO)(PPh3)(2) which has an Si-N distance of 3.176(6) Angstrom.

引用

页码：837 / 838

页数：2

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