The synthesis and crystal structure of the first metal-bound stannatrane complex Os(Sn[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2:: structural comparisons with the analogous silatrane complex Os(Si[OCH2CH2]3N)(η2-S2CNMe2)(CO)(PPh3)2

被引：42
|
作者：
Rickard, CEF [1 ]
Roper, WR [1 ]
Woodman, TJ [1 ]
Wright, LJ [1 ]
机构：
[1] Univ Auckland, Dept Chem, Auckland, New Zealand
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 09期
关键词：
D O I：
10.1039/a901408j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first metal substituted stannatrane,Os(Sn-[OCH2CH2](3)N)(eta(2)-S2CNMe2)(CO)(PPh3)(2), has been synthesised by reaction between triethanolamine and the triiodostannyl osmium complex Os(SnI3)(eta(2)-S2CNMe2)-(CO)(PPh3)(2): the transannular Sn-N distance of 2.422(4) Angstrom indicates a bonding interaction which is not seen in the corresponding silatranyl complex Os(Si[OCH2CH2](3)N)(eta(2)-S2CNMe2)(CO)(PPh3)(2) which has an Si-N distance of 3.176(6) Angstrom.
引用
收藏
页码：837 / 838
页数：2
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