Single-electron reduction of C60 with a carbon radical:: formation of the Crystal Violet cation-fulleride ion salt

被引：23

作者：

Kitagawa, T ^{[1
]}

Lee, Y ^{[1
]}

Takeuchi, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 16期

关键词：

D O I：

10.1039/a903911b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Whereas many carbon radicals are known to add to C-60, the reaction of Crystal Violet radical 1(.) with C-60 resulted in single-electron transfer, leading to a carbocation-carbanion salt 1(+)C(60)(.-): the product was isolated as microcrystalline powder and was characterized by EPR, VIS-NIR and NMR spectroscopy.

引用

页码：1529 / 1530

页数：2

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