Epitaxial Crystallization Behavior of Poly(butylene adipate) on Orientated Poly(butylene succinate) Substrate

被引：13

作者：

Wang, Haijun ^{[1
,2
]}

Gao, Zhijin ^{[1
,2
]}

Yang, Xi ^{[1
]}

Liu, Kun ^{[1
]}

Zhang, Min ^{[3
]}

Qiang, Xihuai ^{[1
]}

Wang, Xuechuan ^{[1
]}

机构：

[1] Shaanxi Univ Sci & Technol, Coll Bioresources Chem & Mat Engn, Xian 710021, Shaanxi, Peoples R China

[2] Shaanxi Univ Sci & Technol, Natl Demonstrat Ctr Expt Light Chem Engn Educ, Xian 710021, Shaanxi, Peoples R China

[3] Shaanxi Univ Sci & Technol, Sch Environm Sci & Engn, Xian 710021, Shaanxi, Peoples R China

来源：

POLYMERS | 2018年 / 10卷 / 02期

关键词：

poly(butylene succinate); poly(butylene adipate); blend; epitaxy; ISOTACTIC POLYPROPYLENE; POLYETHYLENE SUBSTRATE; ENZYMATIC DEGRADATION; MELT CRYSTALLIZATION; POLYMORPHIC CRYSTALS; THIN-FILM; BLENDS; TEMPERATURE; MORPHOLOGY; PHASE;

D O I：

10.3390/polym10020110

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The crystallization behavior of poly(butylene adipate) (PBA) in the sheared PBS/PBA blend, as well as on highly orientated poly(butylene succinate) (PBS) substrate, was studied by means of DSC, POM, Raman microscopy, and XRD. The results showed that the pre-existing orientated PBS crystals exhibit a very strong nucleation ability toward PBA as reflected by the increased crystallization temperature and the occurrence of heteroepitaxy and transcrystallization of PBA on the PBS substrate. The epitaxial crystallization of PBA on the PBS substrate results in the formation of alpha-form PBA crystals in any crystallization conditions.

引用

页数：13

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