Organocatalytic enantioselective photoreactions

被引：72
|
作者：
Wessig, P [1 ]
机构：
[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 14期
关键词：
asymmetric catalysis; enantioselectivity; photochemistry; photoincluced electron transfer; sensitizers;
D O I：
10.1002/anie.200503908
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Light at the end of the tunnel. The reports on organocatalytic photoreactions that are also enantioselective are few and far between. Recently published work now highlights a breakthrough. When special catalysts derived from Kemp's triacid were used, selectivities of up to 70% ee were achieved (see scheme; PET = photoinduced electron transfer). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2168 / 2171
页数：4
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