Cyclic single-molecule magnet in heterospin system

被引：81
|
作者：
Yoshihara, Daisuke [1 ]
Karasawa, Satoru [1 ]
Koga, Noboru [1 ]
机构：
[1] Kyushu Univ, Grad Sch Pharmaceut Sci, Higashi Ku, Fukuoka 8128582, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 32期
关键词：
D O I：
10.1021/ja802895d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The 2:2 complex of Co-carbene is generated by photolysis of [Co(hfpip)(2) (D2py(2)(TBA))](2), 1, having a cyclic structure functioning as a single-molecule magnet with U-eff = 96 K and H-c = 10 kOe at 1.9 K after annealing at 70 K.
引用
收藏
页码：10460 / +
页数：3
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