An Undecanuclear FeIII Single-Molecule Magnet

被引：71
|
作者：
Ako, Ayuk M. [1 ,2 ]
Mereacre, Valeriu [1 ]
Lan, Yanhua [1 ]
Wernsdorfer, Wolfgang [3 ]
Clerac, Rodolphe [4 ,5 ]
Anson, Christopher E. [1 ]
Powell, Annie K. [1 ,2 ]
机构：
[1] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany
[2] Karlsruhe Inst Technol, Inst Nanotechnol, Forschungszentrum Karlsruhe, D-76021 Karlsruhe, Germany
[3] CNRS, Inst Neel, F-38042 Grenoble 9, France
[4] Univ Bordeaux, UPR 8641, F-33600 Pessac, France
[5] CNRS, Ctr Rech Paul Pascal, Equipe Mat Mol Magnet, UPR 8641, F-33600 Pessac, France
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 01期
关键词：
CLUSTERS; IRON(III); COMPLEXES; BEHAVIOR;
D O I：
10.1021/ic901747w
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The undecanuclear complex in [Fe-11(III)(mu(4)-O)(3)(mu(3)-O)(4)(L)(3)(mu-O2CCMe3)(12)]Cl center dot 5MeCN has been synthesized and characterized by single-crystal X-ray crystallography. Mossbauer spectroscopy and bulk susceptibility studies reveal that the complex has an S = 13/2 spin ground state and exhibits single-molecule-magnet behavior.
引用
收藏
页码：1 / 3
页数：3
相关论文
共 50 条
  • [1] The {FeIII[FeIII(L1)2]3} star-type single-molecule magnet
    Saalfrank, Rolf W.
    Scheurer, Andreas
    Bernt, Ingo
    Heinemann, Frank W.
    Postnikov, Andrei V.
    Schuenemann, Volker
    Trautwein, Alfred X.
    Alam, Mohammad S.
    Rupp, Holger
    Mueller, Paul
    [J]. DALTON TRANSACTIONS, 2006, (23) : 2865 - 2874
  • [2] A cyano-based octanuclear {FeIII4NiII4} single-molecule magnet
    Zhang, Yuanzhu
    Mallik, Uma Prasad
    Rath, Nigam
    Yee, Gordon T.
    Clerac, Rodolphe
    Holmes, Stephen M.
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (27) : 4953 - 4955
  • [3] Pyrazolylborates and Their Importance in Tuning Single-Molecule Magnet Properties of {FeIII2NiII} Complexes
    Zhang, Yuan-Zhu
    Mallik, Uma P.
    Rath, Nigam P.
    Clerac, Rodolphe
    Holmes, Stephen M.
    [J]. INORGANIC CHEMISTRY, 2011, 50 (21) : 10537 - 10539
  • [4] A diferrous single-molecule magnet
    Boudalis, Athanassios K.
    Sanakis, Yiannis
    Clemente-Juan, Juan Modesto
    Mari, Alain
    Tuchagues, Jean-Pierre
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 17 (17) : 2409 - 2415
  • [5] A single-molecule magnet with a twist
    Milios, Constantinos J.
    Vinslava, Alina
    Wood, Peter A.
    Parsons, Simon
    Wernsdorfer, Wolfgang
    Christou, George
    Perlepes, Spyros P.
    Brechin, Euan K.
    [J]. Journal of the American Chemical Society, 2007, 129 (01): : 8 - 9
  • [6] Cobalt single-molecule magnet
    Yang, EC
    Hendrickson, DN
    Wernsdorfer, W
    Nakano, M
    Zakharov, LN
    Sommer, RD
    Rheingold, AL
    Ledezma-Gairaud, M
    Christou, G
    [J]. JOURNAL OF APPLIED PHYSICS, 2002, 91 (10) : 7382 - 7384
  • [7] A single-molecule magnet with a "twist"
    Milios, Constantinos J.
    Vinslava, Alina
    Wood, Peter A.
    Parsons, Simon
    Wernsdorfer, Wolfgang
    Christou, George
    Perlepes, Spyros P.
    Brechin, Euan K.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (01) : 8 - 9
  • [8] An Enantiopure FeIII4 Single Molecule Magnet
    Gao, Song
    Zhu, Yuan-Yuan
    Guo, Xiao
    Cui, Chang
    Wang, Bing-Wu
    Wang, Zhe-Ming
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C642 - C643
  • [9] An S=2 cyanide-bridged trinuclear FeIII2NIII single-molecule magnet
    Li, Dongfeng
    Clerac, Rodolphe
    Parkin, Sean
    Wang, Guangbin
    Yee, Gordon T.
    Holmes, Stephen M.
    [J]. INORGANIC CHEMISTRY, 2006, 45 (14) : 5251 - 5253
  • [10] Single-molecule magnet behavior in three cyano-bridged heterometallic FeIII-NiII clusters
    Zhuang, Peng-Fei
    Zhang, Yan-Juan
    Zheng, Hui
    Jiao, Cheng-Qi
    Zhao, Liang
    Wang, Jun-Li
    He, Cheng
    Duan, Chun-Ying
    Liu, Tao
    [J]. DALTON TRANSACTIONS, 2015, 44 (07) : 3393 - 3398
12345