1H NMR spectral studies on the polymerization mechanism of indole and its derivatives

被引：57
|
作者：
Xu, JK [1 ]
Hou, J
Zhou, WQ
Nie, GM
Pu, S
Zhang, SS
机构：
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
[2] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2006年 / 63卷 / 03期
关键词：
conducting polymers; polyindoles; polymerization mechanism; hydrogen nuclear magnetic resonance; boron trifluoride diethyl etherate;
D O I：
10.1016/j.saa.2005.06.025
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The existence of N-H bond according to the hydrogen nuclear magnetic resonance (H-1 NMR) spectra of polyindole and its derivatives, such as poly(5-bromoindole), poly(5-cyanoindole), poly(5-nitroindole), poly (5-methylindole), proved polymerization of high-quality polyindoles, which were electrosynthesized from middle strong Lewis acid boron trifluoride diethyl etherate (BFEE) and its mixed electrolytes with additional diethyl ether, occurred at 2,3-position. The elongation of the conjugation length made the chemical shift of all the protons of polyindoles to lower field in comparison with those of monomers. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：723 / 728
页数：6
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