Chemoenzymatic synthesis of a novel ligand for rhodium-catalysed asymmetric hydrogenation

被引：12

作者：

Adger, B

Berens, U

Griffiths, MJ

Kelly, MJ

McCague, R

Miller, JA

Palmer, CF

Roberts, SM

Selke, R

Vitinius, U

Ward, G

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 7ZD,MERSEYSIDE,ENGLAND

[2] CHIROSCI PLC,CAMBRIDGE CB4 4WE,ENGLAND

[3] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND

[4] UNIV ROSTOCK,MAX PLANCK GESELL FORDERUNG WISSENSCH EV,D-18055 ROSTOCK,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a704136e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogenation of alkenes 7a-g using a chiral rhodium catalyst 6 (based on a bicyclo[3.2.0]heptane framework) takes place to give the phenylalanine derivatives 8a-g with remarkably high stereoselectivity (59-92% ee).

引用

页码：1713 / 1714

页数：2

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