Synthesis of 5-Substituted N-Nitro-2,4-dihydro-3H-1,2,4-triazol-3-imines

被引：0
|
作者：
Ozerova, O. Yu. [1 ]
Efimova, T. P. [1 ]
Novikova, T. A. [1 ]
机构：
[1] Herzen State Pedag Univ Russia, St Petersburg 19186, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2020年 / 90卷 / 08期
关键词：
N-amino-N ''-nitroguanidin; carboxylic acid chlorides; N-(N ''-nitroguanidino) carboxamides; N-nitro-1; 2; 4-triazol-3-imines; 2-NITROGUANIDINE DERIVATIVES; 1-AMINO-2-NITROGUANIDINE;
D O I：
10.1134/S1070363220080046
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of N-amino-N ''-nitroguanidine with carboxylic acid chlorides at room temperature gave the corresponding N-(N ''-nitroguanidino)carboxamides which underwent cyclization on heating in aqueous alkali to affordN-nitro-1,2,4-triazol-3-imines. The latter were also synthesized in a one-pot fashion. The products were characterized by H-1 and C-13-{H-1}, IR, and UV spectra.
引用
收藏
页码：1403 / 1407
页数：5
相关论文
共 50 条
  • [1] Synthesis of 5-Substituted N-Nitro-2,4-dihydro-3H-1,2,4-triazol-3-imines
    O. Yu. Ozerova
    T. P. Efimova
    T. A. Novikova
    Russian Journal of General Chemistry, 2020, 90 : 1403 - 1407
  • [2] PICRYL DERIVATIVES OF 5-NITRO-2,4-DIHYDRO-3H-1,2,4-TRIAZOL-3-ONE
    COBURN, MD
    LEE, KY
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 1990, 27 (03) : 575 - 577
  • [3] Photoreaction of C-60 with NTO (5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one)
    Pace, MD
    PROCEEDINGS OF THE SYMPOSIUM ON RECENT ADVANCES IN THE CHEMISTRY AND PHYSICS OF FULLERENES AND RELATED MATERIALS, VOL 3, 1996, 96 (10): : 223 - 227
  • [4] Ketoalkylation of 2,4-dihydro-3H-1,2,4-triazol-3-one in dimethylsulfoxide
    Voronkov, M. G.
    Yarosh, N. O.
    Zhilitskaya, L. V.
    Shagun, L. G.
    Dorofeev, I. A.
    Larina, L. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2013, 83 (12) : 2340 - 2342
  • [5] 2,4-DIHYDRO-3H-1,2,4-TRIAZOL-3-ONES AS ANTICONVULSANT AGENTS
    KANE, JM
    BARON, BM
    DUDLEY, MW
    SORENSEN, SM
    STAEGER, MA
    MILLER, FP
    JOURNAL OF MEDICINAL CHEMISTRY, 1990, 33 (10) : 2772 - 2777
  • [6] Ketoalkylation of 2,4-dihydro-3H-1,2,4-triazol-3-one in dimethylsulfoxide
    M. G. Voronkov
    N. O. Yarosh
    L. V. Zhilitskaya
    L. G. Shagun
    I. A. Dorofeev
    L. I. Larina
    Russian Journal of General Chemistry, 2013, 83 : 2340 - 2342
  • [7] FACILE SYNTHESIS OF NOVEL PESTICIDAL 5-ALKOXYCARBONYLAMINO-2,4-DIHYDRO-3H-1,2,4-TRIAZOL-3-ONES
    MOHAN, K
    BHRAMARAMBA, K
    VENKATARATNAM, RV
    CHEMISTRY & INDUSTRY, 1978, (04) : 125 - 126
  • [8] Efficient Synthesis of 5-(Substituted)benzyl-2,4-Dihydro-3H-1,2,4-Triazol-3-Ones Using Microwave Irradiation
    Kahveci, Bahittin
    Mentese, Emre
    Ozil, Musa
    Bekircan, Olcay
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 2013, 35 (02): : 411 - 414
  • [9] Crystal packing and molecular dynamics studies of the 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one crystal
    Sorescu, DC
    Thompson, DL
    JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (18): : 3605 - 3613
  • [10] SYNTHESIS OF 4-AMINO-2-ARYL-2,4-DIHYDRO-3H-1,2,4-TRIAZOL-3-ONES
    EHRHARDT, H
    HEUBACH, G
    MILDENBERGER, H
    LIEBIGS ANNALEN DER CHEMIE, 1982, (05): : 994 - 1000
12345