PICRYL DERIVATIVES OF 5-NITRO-2,4-DIHYDRO-3H-1,2,4-TRIAZOL-3-ONE

被引：13
|
作者：
COBURN, MD
LEE, KY
机构：
[1] University of California, Los Alamos National Laboratory, Los Alamos, New Mexico
来源：
JOURNAL OF HETEROCYCLIC CHEMISTRY | 1990年 / 27卷 / 03期
关键词：
D O I：
10.1002/jhet.5570270318
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of 5‐nitro‐2,4‐dihydro‐3H‐1,2,4‐triazol‐3‐one (1) with picryl fluoride (PkF) in 1‐methyl‐2‐pyrrolidinone (NMP) gave a mixture of a monopicryl and a dipicryl derivative of 1 in a ratio of 2:1, respectively, regardless of the initial concentrations of 1 and PkF. The products were identified as 5‐nitro‐2‐picryl‐2,4‐dihydro‐3H‐1,2,4‐triazol‐3‐one (2) by X‐ray crystallography and 5‐nitro‐2,4‐dipicryl‐2,4‐dihydro‐3H‐1,2,4‐triazol‐3‐one (4) by 15N labeling experiments. Copyright © 1990 Journal of Heterocyclic Chemistry
引用
收藏
页码：575 / 577
页数：3
相关论文
共 50 条
  • [1] Photoreaction of C-60 with NTO (5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one)
    Pace, MD
    [J]. PROCEEDINGS OF THE SYMPOSIUM ON RECENT ADVANCES IN THE CHEMISTRY AND PHYSICS OF FULLERENES AND RELATED MATERIALS, VOL 3, 1996, 96 (10): : 223 - 227
  • [2] Crystal packing and molecular dynamics studies of the 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one crystal
    Sorescu, DC
    Thompson, DL
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (18): : 3605 - 3613
  • [3] Computational study of NTO (5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one) tautomeric properties in aqueous solution
    Golius, Anastasiia
    Gorb, Leonid
    Scott, Andrea Michalkova
    Hill, Frances C.
    Leszczynski, Jerzy
    [J]. STRUCTURAL CHEMISTRY, 2015, 26 (5-6) : 1281 - 1286
  • [4] Theoretical and experimental study of the inelastic neutron scattering spectra of β-5-Nitro-2,4-dihydro-3H-1,2,4-triazol-3-one
    Ciezak, JA
    Trevino, SF
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2005, 732 (1-3): : 211 - 218
  • [5] Computational study of NTO (5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one) tautomeric properties in aqueous solution
    Anastasiia Golius
    Leonid Gorb
    Andrea Michalkova Scott
    Frances C. Hill
    Jerzy Leszczynski
    [J]. Structural Chemistry, 2015, 26 : 1281 - 1286
  • [6] Quantum chemical study on 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO) and some of its constitutional isomers
    Turker, Lemi
    Atalar, Taner
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (03) : 1333 - 1344
  • [7] Decomposition of 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one (NTO):: Energetics associated with several proposed initiation routes
    Meredith, C
    Russell, TP
    Mowrey, RC
    McDonald, JR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (02): : 471 - 477
  • [8] Free radicals from photolysis of (NTO) 5-nitro-2,4-dihydro-3h-1,2,4-triazol-3-one studied by EPR spin trapping
    Pace, MD
    Fan, L
    Burkey, TJ
    [J]. DECOMPOSITION, COMBUSTION, AND DETONATION CHEMISTRY OF ENERGETIC MATERIALS, 1996, 418 : 127 - 133
  • [9] Ketoalkylation of 2,4-dihydro-3H-1,2,4-triazol-3-one in dimethylsulfoxide
    Voronkov, M. G.
    Yarosh, N. O.
    Zhilitskaya, L. V.
    Shagun, L. G.
    Dorofeev, I. A.
    Larina, L. I.
    [J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2013, 83 (12) : 2340 - 2342
  • [10] Ketoalkylation of 2,4-dihydro-3H-1,2,4-triazol-3-one in dimethylsulfoxide
    M. G. Voronkov
    N. O. Yarosh
    L. V. Zhilitskaya
    L. G. Shagun
    I. A. Dorofeev
    L. I. Larina
    [J]. Russian Journal of General Chemistry, 2013, 83 : 2340 - 2342
12345