Unique copper-salen complex: an efficient catalyst for N-arylations of anilines and imidazoles at room temperature

被引：59
|
作者：
Gogoi, Ankur [1 ]
Sarmah, Gayatri [1 ]
Dewan, Anindita [1 ]
Bora, Utpal [1 ,2 ]
机构：
[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India
[2] Tezpur Univ, Dept Chem Sci, Tezpur 784028, Assam, India
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 01期
关键词：
Amine; Arylboronic acid; Chan-Lam; Copper; Imidazole; Water; CROSS-COUPLING REACTIONS; C-N; ARYLBORONIC ACIDS; HETEROCYCLIC CARBENES; HIGHLY EFFICIENT; ARYL BROMIDES; HETEROARYL BROMIDES; ALIPHATIC-AMINES; BOND FORMATION; LIGAND-FREE;
D O I：
10.1016/j.tetlet.2013.10.084
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have reported here the catalytic activity of a unique Cu-salen type complex in N-arylation of anilines with arylboronic acids in water. The protocol is found to be applicable for a wide range of electronically diversified arylboronic acids and anilines with excellent yields of the isolated product. Further the scope of this protocol has been extended to the synthesis of various N-aryl imidazoles in iso-propanol. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：31 / 35
页数：5
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