An in situ study of resin-assisted solvothermal metal-organic framework synthesis

被引：6

作者：

Moorhouse, Saul J. ^{[1
]}

Wu, Yue ^{[1
]}

O'Hare, Dermot ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Chem Res Lab, Mansfield Rd, Oxford OX1 3TA, England

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2016年 / 236卷

基金：

英国工程与自然科学研究理事会;

关键词：

Coordination polymer; Metal-organic framework; Solvothermal synthesis; In situ diffraction; Resin assisted synthesis; X-RAY-DIFFRACTION; CRYSTALLIZATION KINETICS; FUNCTIONALIZED POLYMERS; COORDINATION POLYMERS; TIME; DICARBOXYLATES; NANOPARTICLES; COBALT(II); EVOLUTION; LIGANDS;

D O I：

10.1016/j.jssc.2015.07.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A newly developed in situ monochromatic high-energy X-ray diffraction setup was used to investigate the synthesis of MOFs using cation-impregnated polymer resin beads as a ion source. The Co-NDC-DMF (NDC=2,6-naphthalenedicarboxylate; DMF=dimethylformamide) system was investigated, a system which is known to produce at least three distinct frameworks. It was found that the resin-assisted synthesis results in the preferential formation of a topology previously impossible to synthesise in bulk, while the comparable nitrate-salt synthesis appeared to form an alternative phases. It was also found that the resin-assisted synthesis is highly diffusion-controlled. (C) 2015 Elsevier Inc. All rights reserved.

引用

页码：209 / 214

页数：6

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