An in situ study of resin-assisted solvothermal metal-organic framework synthesis

被引：6
|
作者：
Moorhouse, Saul J. [1 ]
Wu, Yue [1 ]
O'Hare, Dermot [1 ]
机构：
[1] Univ Oxford, Dept Chem, Chem Res Lab, Mansfield Rd, Oxford OX1 3TA, England
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2016年 / 236卷
基金：
英国工程与自然科学研究理事会;
关键词：
Coordination polymer; Metal-organic framework; Solvothermal synthesis; In situ diffraction; Resin assisted synthesis; X-RAY-DIFFRACTION; CRYSTALLIZATION KINETICS; FUNCTIONALIZED POLYMERS; COORDINATION POLYMERS; TIME; DICARBOXYLATES; NANOPARTICLES; COBALT(II); EVOLUTION; LIGANDS;
D O I：
10.1016/j.jssc.2015.07.035
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A newly developed in situ monochromatic high-energy X-ray diffraction setup was used to investigate the synthesis of MOFs using cation-impregnated polymer resin beads as a ion source. The Co-NDC-DMF (NDC=2,6-naphthalenedicarboxylate; DMF=dimethylformamide) system was investigated, a system which is known to produce at least three distinct frameworks. It was found that the resin-assisted synthesis results in the preferential formation of a topology previously impossible to synthesise in bulk, while the comparable nitrate-salt synthesis appeared to form an alternative phases. It was also found that the resin-assisted synthesis is highly diffusion-controlled. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码：209 / 214
页数：6
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