Metal nanoparticles or metal oxide nanoparticles, an efficient and promising family of novel heterogeneous catalysts in organic synthesis

被引:79
|
作者
Wang, Sujing
Wang, Zhiyong [1 ]
Zha, Zhenggen
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Joint Lab Green Synthet Chem, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON-CARBON BOND; LIGAND-FREE CONDITIONS; BARBIER-TYPE REACTION; PALLADIUM NANOPARTICLES; ROOM-TEMPERATURE; PD NANOPARTICLES; AQUEOUS-MEDIA; ARYL HALIDES; COUPLING REACTION; HIGHLY EFFICIENT;
D O I
10.1039/b913539a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Recently, organic reactions catalyzed by metal/metal oxide nanoparticles (NPs) has attracted much attention. The notable advantages of this novel family of heterogeneous catalysts, such as high catalytic activity, good recyclability and improved selectivity, extend to a wide-range of applications in various organic reactions. This perspective provides an overview of the progresses made in metal/metal oxide NPs catalyzed organic reactions achieved in our group. Based on our investigations, we suggest that further exploration is required in two aspects in this area: (1) the effects of the size and shape of NPs on the reaction activity and selectivity, and (2) the effect of the supporting environment of the artificial template on the reaction activity and selectivity.
引用
收藏
页码:9363 / 9373
页数:11
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