Manganese diphosphonate with a ladder-like chain structure exhibiting field-induced magnetic transition

被引：13
|
作者：
Ma, Yunsheng [1 ]
Yuan, Rongxin [1 ]
Zheng, Limin [2 ]
机构：
[1] Changshu Inst Technol, Jiangsu Key Lab Adv Funct Mat, Dept Chem & Mat Engn, Changshu 215500, Jiangsu, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 09期
关键词：
Manganese; Diphosphonate; Magnetic property; Ladder-like chain;
D O I：
10.1016/j.inoche.2009.06.039
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A manganese diphosphonate Mn(hpedpH(2)).3H(2)O [hpedpH(4)=1-hydroxy-2-(2-pyridyl)ethylidene-1,1diphosphonic acid] has been synthesized under hydrothermal conditions. It shows a ladder-like chain structure in which the edge-shared (MnO6) octahedral are linked by (CPO3) tetrahedral through corner-sharing. The magnetization measurements reveal that dominant antiferromagnetic interactions are mediated between the magnetic centers and the compound experiences a field-induced magnetic transition at low temperature. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：860 / 863
页数：4
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