The conversion of methanol to hydrocarbons over dealuminated zeolite H-beta

被引:60
|
作者
Bjorgen, M [1 ]
Kolboe, S [1 ]
机构
[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
关键词
beta-zeolite; dealumination; deactivation; methanol-to-hydrocarbons;
D O I
10.1016/S0926-860X(01)00865-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Conversion of methanol-to-hydro carbons has been studied over beta-zeolites with varying contents of aluminum, obtained by dealumination of the parent sample with oxalic acid. It was found that the dealumination leads to catalysts which are more resistant to deactivation. The total amount of methanol which might be converted to hydrocarbons before the catalyst becomes completely deactivated increased. The conversion capacity is higher at high reactant feed rates. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码:285 / 290
页数:6
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