Octafluorobiphenyl-4,4′-dicarboxylate as a ligand for metal-organic frameworks: progress and perspectives

被引：3
|
作者：
Cheplakova, Anastasia M. [1 ,2 ]
Samsonenko, Denis G. [1 ,2 ]
Fedin, Vladimir P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
来源：
PURE AND APPLIED CHEMISTRY | 2020年 / 92卷 / 07期
基金：
俄罗斯科学基金会;
关键词：
gas sorption; hydrophobicity; Mendeleev-21; metal-organic frameworks; perfluorinated ligands; photoluminescence; CRYSTAL-STRUCTURE; PADDLE-WHEEL; FUNCTIONALIZATION; ADSORPTION; STABILITY; COMPLEXES; PRESSURE; DESIGN; UIO-66; ACID;
D O I：
10.1515/pac-2019-1210
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
While metal-organic frameworks based on aromatic carboxylates are very numerous and well investigated, the chemistry of their fully fluorinated analogues is at the very beginning. This minireview aims at summarizing all metal complexes with octafluorobiphenyl-4,4'-dicarboxylate (oFBPDC(2-)) anion and in particular, porous coordination polymers, their syntheses, crystal structures and functional properties highlighting the importance of further investigation of such systems.
引用
收藏
页码：1081 / 1092
页数：12
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