Three-dimensional metal-organic frameworks constructed from bix and 1,2,4-benzenetricarboxylate

被引：50
|
作者：
Yao, Jing [1 ]
Lu, Zhen-Da [1 ]
Li, Yi-Zhi [1 ]
Lin, Jian-Guo [1 ]
Duan, Xian-Ying [1 ]
Gao, Song [2 ]
Meng, Qing-Jin [1 ]
Lu, Chang-Sheng [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
[2] Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
来源：
CRYSTENGCOMM | 2008年 / 10卷 / 10期
关键词：
D O I：
10.1039/b805263h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new metal-organic complexes [Cd-1.5(btrc)(bix)](n) (1) and [Zn-2(btrc)(Hbtrc)(0.5)(bix)(2)](n)(2) (H(3)btrc = 1,2,4-benzenetricarboxylate; bix = 1,4-bis(imidazol-l-ylmethyl)-benzene) have been hydrothermally synthesized and characterized by single crystal X-ray diffraction. Complex 1 represents a three-dimensional (3D) structure based on the 2D sheets and bix pillars. Complex 2 exhibits unique architecture. The two complexes exhibit strong fluorescent emissions in their solid states at room temperature.
引用
收藏
页码：1379 / 1383
页数：5
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