Aquadichloro(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)nickel(II)

被引:5
|
作者
Ding, CF
Miao, YF
Tian, BQ
Li, XM
Zhang, SS [1 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Shandong 266042, Peoples R China
[2] Qingdao Radio & TV Univ, Shandong 266001, Peoples R China
关键词
D O I
10.1107/S1600536806013250
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [ NiCl2( C14H12N2)( H2O)], there are two molecules in the asymmetric unit. Each Ni atom is five-coordinate in a geometry between trigonal-bipyramidal and tetragonal-pyrimidal. Molecules are linked into a three-dimensional framework by O-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl hydrogen bonds. The packing is further stabilized by pi-pi interactions between the phenanthroline ring systems.
引用
收藏
页码:M1062 / M1063
页数:2
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