One-Dimensional Mn(III) Coordination Polymer Exhibiting Ferromagnetic Coupling

被引：20
|
作者：
Kou, Hui-Zhong [1 ]
Wang, Yi-Tong [1 ]
Luo, Wang-Xi [1 ]
Xie, Qi-Wei [1 ]
Tao, Jun [2 ]
Cui, Ai-Li [1 ]
Shen, De-Zhong [1 ]
机构：
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[2] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 11期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1021/cg800560x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mn(III) complexes of 1-(2-hydroxybenzamido)-2-((2-hydroxy-3-methoxybenzylidene)amino)ethane (H(3)L), mononuclear [Mn(L)(MeOH)(H(2)O)] (1) and amido-bridged one-dimensional [Mn(L)(H(2)O)](infinity) (2), have been synthesized by the reaction of MnAc3-2H20 with H3L. Magnetic studies revealed that complex 2 exhibits intermetallic ferromagnetic coupling, which is the first one-dimensional highspin Mn(III) complex with ferromagnetic behavior.
引用
收藏
页码：3908 / 3910
页数：3
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