Inorganic Chelate Rings in Organolead(IV) Derivatives of Organophosphorus Ligands from 6-Membered to 16-Membered Rings

被引:2
|
作者
Varga, Richard [1 ]
Drake, John E. [2 ]
Silvestru, Cristian [1 ]
机构
[1] Univ Babes Bolyai, Dept Chem, RO-3400 Cluj Napoca, Romania
[2] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada
关键词
dichalcogenoimidodiphosphinato ligands; inorganic rings; organoPb(IV) complexes;
D O I
10.1080/10426500108546587
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New organolead(IV) complexes of the type R3Pb[OPPh2)(XPPh2)N], R2Pb[OPPh2)(XPPh2)N](2) (R = Me, Ph; X = O, S) Me3Pb(O2PPh2) have been prepared and characterized by IR and multinuclear (H-1, C-13, P-31) NMR spectroscopy. The X-ray molecular structure of the Me2Pb[OPPh2)(2)N](2) and Me3Pb(O2PPh2) is discussed.
引用
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页码:47 / 50
页数:4
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